SODIUM CITRATE, USP (ANHYDROUS) 2.5KG by Letco Medical Safety Data Sheet Section 1: Identification Common Name/Trade Name SODIUM CITRATE ANHYDROUS USP Supplier Information Letco Medical, LLC 1316 Commerce Drive NW Decatur, AL 35601 1 (800) 239-5288 +1 (734) 843-4693 IN CASE OF EMERGENCY: Chemtrec 1 (800) 424-9300 (24 hours) Product Synonym(s) Trisodium citrate; 2-Hydroxy-1,2,3-propanetricarboxylic acid trisodium salt. Relevant Use(s) of Product Manuf acture or Compounding of Substances Section 2: Hazards Identification Classification of Substance or Mixture Not classif ied Signal Word None Hazard Statement(s) N/A Pictogram(s) N/A Precautionary Statement(s) N/A Hazards Not Otherwise Classified Combustible Dust Ingredient(s) with Unknown Toxicity No data available Section 3: Composition/Information on Ingredients Chemical Name Sodium citrate Common Name Sodium Citrate Anhydrous CAS Number 68-04-2 Impurities and/or Stabilizing Additives No data available Section 4: First Aid Measures General Advice When symptoms persist or in all cases of doubt seek medical advice. Notes to Physician: Treat symptomatically. If Inhaled Move to fresh air. In Case of Skin Contact Wash of f with warm water and soap. In Case of Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. If Swallowed Clean mouth with water and af terwards drink plenty of water. Most Important Symptoms and Effects Eyes: Contact with eyes may cause mechanical irritation. Skin: Product dust may cause mild, mechanical irritation. Inhalation: Dust may cause irritation of respiratory tract. Ingestion: Health injuries are not known or expected under normal use. Section 5: Fire Fighting Measures Suitable Extinguishing Media Suitable Extinguishing Media: Water. Carbon dioxide (CO2) Foam. Dry powder. Dry chemical. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Special Hazards Arising From the Substance/Mixture Hazardous Combustion Products: Carbon monoxide (CO), Carbon dioxide (CO2). Specif ic Hazards Arising from the Chemical: Combustible material. Sensitivity to static discharge: Yes. (as dust). Special PPE and/or Precautions for Firefighters As in any f ire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and f ull protective gear. Section 6: Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Ensure adequate ventilation. Avoid dust f ormation. Avoid sparks, f lames, static electricity discharges, etc.in the presence of dust. Methods and Materials Used for Containment Keep in suitable, closed containers f or disposal. Prevent f urther leakage or spillage if saf e to do so. Cleanup Procedures Shovel or sweep up. Sweep up and shovel into suitable containers f or disposal. Avoid dust f ormation. Af ter cleaning, f lush away traces with water. Page 1 of 4 Section 7: Handling and Storage Precautions for Safe Handling Ensure adequate ventilation. Avoid dust f ormation in conf ined areas. Fine dust dispersed in air may ignite. Ref er to NFPA 61, "Standard f or the Prevention of Fires and Dust Explosions in Agricultural and Food Processing Facilities." Conditions for Safe Storage Keep in a dry, cool and well-ventilated place. Section 8: Exposure Controls/Personal Protection Components with Workplace Control Parameters Exposure Limits: Where ther is airborne dust, exposure limits pertaining to 'particulates not otherwise regulated' have been given: Chemical Name/ACGIH TLV/OSHA PEL/Mexico/NIOSH: Particulates not otherwise regulated/TWA: 10 mg/m³ inhalable particles, recommended, TWA: 3 mg/m³ respirable particles, recommended/TWA: 15mg/m³ total dust, TWA: 5 mg/m³ respirable fraction/not listed/not listed. Appropriate Engineering Controls Ensure adequate ventilation, especially in conf ined areas. Handle in accordance with good industrial hygiene and saf ety practice. PPE - Eye/Face Protection If exposed to airborne dust, appropriate saf ety glasses with side-shields or saf ety goggles are recommended. PPE - Skin Protection Protective clothing and gloves may be worn to reduce the potential of mechanical irritation. PPE - Body Protection Protective clothing and gloves may be worn to reduce the potential of mechanical irritation. PPE - Respiratory Protection If exposed to airborne dust, use appropriate NIOSH approved (or equivalent) respiratory protection. Section 9: Physical and Chemical Properties Appearance Colorless to White Powder / Crystalline Granules Upper/Lower Flammability or Explosive Limits No data available Odor Odorless Vapor Pressure Not applicable Odor Threshold No data available Vapor Density Not applicable pH approx 8.0 Relative Density No data available Melting Point/Freezing Point Decomposes bef ore melting Solubility Insoluble in Alcohol. Water Solubility: approx 36% Initial Boiling Point and Boiling Range Not applicable Flash Point Not applicable Evaporation Rate Not applicable Flammability (Solid, Gas) No data available Partition Coefficient No data available Auto-Ignition Temperature No data available Decomposition Temperature No data available Viscosity No data available Section 10: Stability and Reactivity Reactivity No data available Chemical Stability Stable under normal conditions Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Avoid dust f ormation Incompatible Materials No materials to be especially mentioned Hazardous Decomposition Products None under normal use. Thermal decomposition may lead to release of : Carbon monoxide (CO), Carbon dioxide (CO2) Page 2 of 4 Section 11: Toxicological Information Acute Toxicity - LD50 Oral LD50 Oral >8000 mg/kg bw (rat) Acute Toxicity - Inhalation No data available Acute Toxicity - Dermal No data available Acute Toxicity - Eye No data available Skin Corrosion/Irritation Based on available data, not, or only slightly irritating. Serious Eye Damage/Irritation Based on available data, no evidence of serious eye damage/irritation. Respiratory or Skin Sensitazation Based on available data, not expected to be a skin or respiratory sensitizer. Germ Cell Mutagenicity Based on available data, the classif ication criteria are not met. Carcinogenicity IARC No data available Carcinogenicity ACGIH TWA: 10 mg/m³ inhalable particles, recommended. TWA : 3mg/m³ respirable particles, recommended Carcinogenicity NTP No data available Carcinogenicity OSHA OSHA PEL: TWA: 15 mg/m³ total dust, TWA: 5 mg/m³ respirable fraction Reproductive Toxicity Based on available data, no evidence of reproductive toxicity. Specific Target Organ Toxicity - Single Exposure No evidence of toxicity. Specific Target Organ Toxicity - Repeated Exposure No evidence of toxicity. Aspiration Hazard Based on available data, no known aspiration hazard. Section 12: Ecological Information Toxicity Contains no substances known to be hazardous to the environment. Chemical name/Fresh Water Algae/Acute Fish Toxicity/Daphnia (Water f lea): Sodium citrate/EC50:96h 18000 - 32000 mg/L (Chlorella vulgaris)/LC50: 96h 18000-32000 mg/L (Poecilia reticulata)/EC50: 48h 5600 - 10000 mg/L (Daphnia magna) Persistence and Degradability Inherently biodegradable. Bio-accumulative Potential No data available Mobility in Soil No data available Other Adverse Effects No data available Section 13: Disposal Considerations Waste Treatment Methods Product Dispose of in compliance with the laws and regulations pertaining to this product in your jurisdiction. Can be landf illed or incinerated, when in compliance with local regulations. Waste Treatment Methods Packaging Empty containers should be decontaminated and taken f or local recycling, recovery or waste disposal. Special Precautions Landfill or Incinerations No data available Other Information No data available Section 14: Transport Information UN Number Not dangerous goods UN Proper Shipping Name N/A Transport Hazard Class(es) N/A Packaging Group N/A Environmental Hazards N/A Section 15: Regulatory Information International Inventories: The components of this product are reported in the f ollowing inventories Yes/No: TSCA/Yes, DSL/Yes, NDSL/No, EINECS/Yes 200-675-3, ELINCS/No, AICS/Yes, ENCS ISHL/Yes (2)-1323, CHINA/Yes, PICCS/Yes, KECL/Yes KE-20843, NZIoC/Yes. USA: Federal Regulations: Ozone Depleting Substances: No Class I or Class II material is known to be used in the manuf acture of , or contained in, this product. SARA 313: Section 313 of Title III of the Superf und Amendments and Reauthorization Act of 1986 (SARA). This product is not known to contain any chemicals which are subject to reporting requirements of the Act or regulations contained in 40 CFR 372. SARA 302: Section 302 of Title III of the Superf und Amendments and Reauthorization Act of 1986 (SARA). This product is not known to contain any chemicals which are subject to the reporting requirements of the Act or regulations contained in 40 CFR 302. SARA 311/312 Hazardous Categorization: Acute Health Hazard/No, Chronic Health Hazard/No, Fire Hazard/No, Sudden Release of Pressure Hazard/No, Reactive Hazard/No. Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 63) This product is not known to contain any HAPS. State Regulations: State Right-to Know: No known components subject to "Right-To-Know" legislation. Canada: WHMIS Product Classif ication: Not a WHMIS controlled product. Exempt: Food Product per Hazardous Products Act Part II Controlled Products Section 12. WHMIS Ingredient Disclosure List IDL: No known component is listed on the WHMIS ingredients disclosure list. (NPRI) Canadian National Pollutant Release Inventory: No known component is listed on NPRI. This product has been classif ied in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the inf ormation required by the CPR. Mexico: Mexico - Grade: Slight risk, Grade 1. Page 3 of 4 Section 16: Other Information Additional Information Prepared By Lisa Russell Revision Date 01/08/2019 13:37 Disclaimer Letco Medical, LLC believes that the above information is correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. If the product is used as a component in another product, this information may not be applicable. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED ABOVE. Letco Medical shall not be held liable for any loss or damage resulting from handling, storage, use or from contact with the above product. Page 4 of 4
