GLYCERIN 99%, USP (NATURAL) 3840ML by Letco Medical Safety Data Sheet Section 1: Identification Common Name/Trade Name GLYCERIN USP Supplier Information Letco Medical, LLC 1316 Commerce Drive NW Decatur, AL 35601 1 (800) 239-5288 +1 (734) 843-4693 IN CASE OF EMERGENCY: Chemtrec 1 (800) 424-9300 (24 hours) Product Synonym(s) Glycerin Relevant Use(s) of Product Manuf acture or Compounding of Substances Section 2: Hazards Identification Classification of Substance or Mixture Skin corrosion/irritation (Category 2), Serious eye damage/eye irritation (Category 2) Signal Word Warning Hazard Statement(s) H315 Causes skin irritation H319 Causes serious eye irritation Pictogram(s) Precautionary Statement(s) P264 Wash hands thoroughly af ter handling. P280 Wear protective gloves/protective clothing/eye protection/f ace protection. P302+P352 IF ON SKIN Wash with soap and water. P305+P351+P338 IF IN EYES Rinse cautiously with water f or several minutes. Remove contact lenses if present and easy to do. continue rinsing. P332+P313 If skin irritation occurs Get medical advice/attention. P337+P313 If eye irritation persists Get medical advice/attention. P362 Take of f contaminated clothing and wash bef ore reuse. Hazards Not Otherwise Classified No data available Ingredient(s) with Unknown Toxicity No data available Section 3: Composition/Information on Ingredients Chemical Name Glycerin Common Name Glycerin USP CAS Number 56-81-5 Impurities and/or Stabilizing Additives No data available Section 4: First Aid Measures General Advice Note to Physicians: Treat symptomatically. If Inhaled Move to fresh air. If symptom persist, call a physician. In Case of Skin Contact Wash of f immediately with plenty of water f or at least 15 minutes. If skin irritation persist call a physician. In Case of Eye Contact Wash of f immediately with plenty of water, also under the eyelids, f or at least 15 minutes. If symptoms persist, call a physician. If Swallowed Immediate medical attention is not required. Rinse mouth. Drink plenty of water. Do NOT induce vomiting. Most Important Symptoms and Effects Use personal protective equipment as required. Section 5: Fire Fighting Measures Suitable Extinguishing Media Water spray (f og), Dry chemical, Alcohol resistant f oam, Carbon dioxide. (CO2). Special Hazards Arising From the Substance/Mixture Above f lash point, vapor-air mixtures are explosive within f lammable limits noted in section 9. Special PPE and/or Precautions for Firefighters In the event of f ire, wear f ull protective clothing and MSHA/NIOSH (approved or equivalent) self-contained breathing apparatus with f ull f ace piece operated in the pressure-demand or other positive pressure mode. Page 1 of 4 Section 6: Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Use personal protective equipment as required. Avoid contact with eyes and skin. Methods and Materials Used for Containment Use personal protective equipment as required. Dam up. Cover liquid spill with sand, earth or other non combustible absorbent material. Take up mechanically, placing in appropriate containers f or disposal. Clean contaminated surf ace thoroughly. Cleanup Procedures Use personal protective equipment as required. Dam up. Cover liquid spill with sand, earth or other non-combustible absorbent material. Take up mechanically, placing in appropriate containers f or disposal. Clean and contaminated surf ace thoroughly. Prevent entry into waterways, sewers, basement or conf ined areas. Section 7: Handling and Storage Precautions for Safe Handling Use only the adequate ventilation. Use personal protective equipment as required. Conditions for Safe Storage Keep container tightly closed. Keep out of reach of children. Section 8: Exposure Controls/Personal Protection Components with Workplace Control Parameters Component: Glycerin Type: TWA Value: 10 mg/m3 mist Glycerin Value: 15mg/m3 Glycerin Value: TWA Control parameters: 5 mg/m3 mist Glycerin Value: TWA Control parameters: 10 mg/m3 Appropriate Engineering Controls Ensure adequate ventilation, especially in conf ined areas. When using do not eat, drink or smoke. Wash contaminated clothing bef ore reuse. PPE - Eye/Face Protection Tight sealing saf ety goggles. PPE - Skin Protection Suitable protective clothing. PPE - Body Protection Suitable protective clothing. PPE - Respiratory Protection No data available Section 9: Physical and Chemical Properties Appearance Form: Liquid Color: Clear Colorless Upper/Lower Flammability or Explosive Limits No data available Odor Odorless Vapor Pressure (mm Hg) : 1.0033 hPa @ 50C Odor Threshold No data available Vapor Density (Air =1) pH No data available Relative Density No data available Melting Point/Freezing Point Melting Point/Freezing Point: 18 �C / 64 �F Solubility Water Solubility: Miscible in water Initial Boiling Point and Boiling Range Boiling Point/Boiling Range: 290 �C / 554 �F Flash Point 199 �C / 390 �F CC (closed cup) Evaporation Rate No data available Flammability (Solid, Gas) No data available Partition Coefficient -1.76 Auto-Ignition Temperature 393 �C / 739 �F Decomposition Temperature No data available Viscosity No data available Section 10: Stability and Reactivity Reactivity No data available Chemical Stability Stable under normal conditions of use and storage. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Heat, f lames and sparks; Ignition sources; Incompatibles. Incompatible Materials Oxidizing agents, Strong acids, Bases, Chlorine Hazardous Decomposition Products Acrolein: Glyceryle nitrate Page 2 of 4 Section 11: Toxicological Information Acute Toxicity - LD50 Oral LD50 Oral 12600 mg/kg ( Rat ) Acute Toxicity - Inhalation No data available Acute Toxicity - Dermal LD50 Dermal 21900 mg/kg ( Rat ) Acute Toxicity - Eye No data available Skin Corrosion/Irritation No data available Serious Eye Damage/Irritation No data available Respiratory or Skin Sensitazation No data available Germ Cell Mutagenicity No data available Carcinogenicity IARC This product does not contain any carcinogens or potential carcinogens as listed by IARC. Carcinogenicity ACGIH This product does not contain any carcinogens or potential carcinogens or potential carcinogens as listed by ACGIH. Carcinogenicity NTP This product does not contain any carcinogens or potential carcinogens as listed by NTP. Carcinogenicity OSHA This product does not contain any carcinogens or potential carcinogens as listed by OSHA. Reproductive Toxicity Target Organ Ef f ects: Eyes, Kidney, Respiratory system, Skin. Specific Target Organ Toxicity - Single Exposure No data available Specific Target Organ Toxicity - Repeated Exposure No data available Aspiration Hazard No data available Section 12: Ecological Information Toxicity Toxicity to f ish 51 - 57: 96 h Oncorhynchus mykiss mL/L LC50 static Toxicity to daphnia and other aquatic invertebrates 500: 24 h Daphnia magna mg/L EC50. Persistence and Degradability No data available Bio-accumulative Potential No data available Mobility in Soil No data available Other Adverse Effects No data available Section 13: Disposal Considerations Waste Treatment Methods Product Disposal should be in accordance with applicable regional, national and local laws and regulations. Waste Treatment Methods Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Special Precautions Landfill or Incinerations No data available Other Information No data available Section 14: Transport Information UN Number Not dangerous goods. UN Proper Shipping Name N/A Transport Hazard Class(es) N/A Packaging Group N/A Environmental Hazards N/A Section 15: Regulatory Information CERCLA: This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superf und Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specif ic reporting requirements at the local, regional, or state level pertaining to releases of this material. SARA 313: Section 313 of Title III of the Superf und Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories: Acute Health Hazard: Yes Chronic health Hazard: No Fire Hazard: No Sudden release of pressure hazard: No Reactive Hazard: No. U. S Right To Know Regulations: Calif ornia Proposition 65: This product does not contain any Proposition 65 chemicals. Page 3 of 4 Section 16: Other Information Additional Information N/A Prepared By Lisa Russell Revision Date 01/11/2019 14:32 Disclaimer Letco Medical, LLC believes that the above information is correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. If the product is used as a component in another product, this information may not be applicable. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED ABOVE. Letco Medical shall not be held liable for any loss or damage resulting from handling, storage, use or from contact with the above product. Page 4 of 4
